可重复使用热防护材料应用与研究进展

可重复使用热防护系统是为高速重复使用飞行器而发展的关键性技术,涵盖了地球大气环境及非地球大气环境下的弹道式再入、高马赫数巡航等应用场景。根据现有高马赫数飞行器热防护现状,对高马赫数飞行器的主要热防护系统类型、特点和使用场景进行了简要介绍。在此基础上,结合国外里程碑式可重复使用飞行器（X-15、SR-71、航天飞机、X-33、X-37B、Spaceliner等）,梳理了可重复使用热防护材料的应用与研究进展,论述了代表性可重复使用热防护材料的发展、性能、研制进度、特点及应用前景。对国外在可重复使用热防护材料研制中的设计及发展思路,以及所存在的主要问题进行了总结归纳,为可重复使用热防护材料未来的发展提供了思路。     

Advances in fabrication of ceramic corundum abrasives based on sol–gel process

Corundum abrasives with good chemical stability can be fabricated into various free abrasives and bonded abrasive tools that are widely used in the precision machining of various parts. However, these abrasives cannot satisfy the machining requirements of difficult-to-machine materials with high hardness, high strength, and strong wearing resistance. Although superhard abrasives can machine the above-mentioned materials, their dressing and manufacturing costs are high. By contrast, ceramic corundum abrasives fabricated by sol–gel method is a cost-effective product between conventional and superhard abrasives. Ceramic corundum abrasives exhibit self-sharpening and high toughness. In this review, the optimization methods of ceramic corundum abrasive properties are introduced from three aspects: precursor synthesis, particle shaping, and sintering. Firstly, the functional mechanism of seeds and additives on the microstructural and mechanical properties of abrasives is analyzed. Specifically, seeds can reduce the phase transition temperature and improve fracture toughness. The grain size and uniformly dense structure can be controlled by applying an appropriate amount of multicomponent additives. Then, the urgent need of engineering application and machinability of special shape ceramic corundum abrasives is reviewed, and three methods of abrasive shaping are summarized. The micromold replication technique is highly advanced and can be used to prepare functional abrasives. Additionally, the influence of a new sintering method, namely, two-step sintering technique, on the microstructural and mechanical performance of ceramic corundum abrasives is summarized. Finally, the challenge and developmental trend of the optimization of ceramic corundum abrasives are prospected.     

长杆弹侵彻新型复合装甲数值仿真及研究

应用有限元计算程序AUTODYN模拟了由爆炸反应装甲和陶瓷复合装甲组成的新型复合装甲在长杆弹斜侵彻作用下的侵彻过程。根据长杆弹与爆炸反应装甲和陶瓷复合装甲的作用现象,研究了长杆弹对新型复合装甲的侵彻机理以及两者在各时刻的作用规律。所得结论对进行其他复合装甲抗长杆弹侵彻的研究具有一定的参考价值。     

共熔法制备超高温陶瓷基复合材料

首次采用共熔法制备超高温陶瓷基复合材料,三个样品初始组分分别为ZrB_2与鳞片石墨,ZrB_2、TaB_2、SiC及鳞片石墨,ZrB_2、MoSi_2与鳞片石墨。研究结果表明,共熔法制备的复合材料中各相分散均匀,产物中的石墨高度有序,石墨层间距分别为0.335 4、0.335 9与0.337 7 nm,且三者的微晶厚度分别为63.4、51.5及68.7 nm,拉曼光谱结果表明硼已经掺杂进入了石墨的网格结构。所制得的超高温陶瓷基复合材料样品中均存在一定的孔隙率,且制备的超高温陶瓷基复合材料的热导率较低。该方法为一种新型、快速、一步法制备超高温陶瓷基复合材料工艺。     

Machining of SiC ceramic matrix composites: A review

Continuous fiber reinforced SiC ceramic matrix composites (FRCMCs-SiC) are currently the preferred material for hot section components, safety–critical components and braking components (in the aerospace, energy, transportation) with high value, and have triggered the demand for machining. However, the high brittleness, anisotropy, and heterogeneity of materials bring great challenges to machining, due to high mechanical and thermal loads, severe tool wear, and poor machining quality. With the increasing demand of FRCMCs-SiC parts, high-quality and high-efficient machining has become a hot issue. This review paper provides a detailed literature survey on the machining of FRCMCs-SiC. The material removal mechanism, defect form, and interfacial mechanical properties of FRCMCs-SiC were summarized. The machining processes of FRCMCs-SiC were introduced, and their respective advantages and disadvantages were compared. Given the low machinability (high hardness, high brittleness, anisotropy, and heterogeneity) of FRCMCs-SiC, preliminary experiments have proved that ultrasonic-assisted machining and laser-assisted machining have shown unique advantages in reducing force and tool wear, improving machining quality and machining efficiency. The machined surface integrity was discussed, the influence of process parameters on the machined surface quality was analyzed, and the machining defects of FRCMCs-SiC were summarized. But for FRCMCs-SiC, the existing quantitative evaluation of the machined surface integrity was weak and unsystematic.     

不同分子量固态与液态聚碳硅烷的黏度特性

采用GPC、流变仪等分析手段对不同分子量的固态PCS和液态PCS的黏度进行表征.分析了PCS分子量、软化点及黏度特性之间的关系.此外还用热重法对固态和液态PCS陶瓷产率进行表征.结果表明,LPCS在室温黏度较低,陶瓷产率较高(77％),而固态PCS熔体在＞200℃具有较低黏度(500 mPa·s),因此LPCS更适于用作PIP法制备陶瓷基复合材料浸渍前驱体.     

影响SiC陶瓷纤维力学性能的因素评价

在SiC陶瓷纤维整个制备工艺过程中，影响因素繁多而且交叉作用，每个因素的变化都对SiC纤维的力学性能产生很大影响。本文以先驱体转化法为例，针对SiC陶瓷纤维整个制备工艺过程中的四个阶段，综述了各个因素对SiC陶瓷纤维最终力学性能的影响。     

多孔陶瓷等效导热系数的近似计算

提出了一个近似计算多孔陶瓷等效导效系数的公式。该公式综合考虑了孔隙大小，孔隙度以及气相辐射与导热的影响，可用于在任意温度下具有任意孔隙度的多孔陶瓷的等效导热系数的计算，用文献数据检验表明，该公式在高温区有较高的计算精度。     

双功能陶瓷膜生物反应器处理污水的实验研究

针对目前膜生物反应器运行过程中膜易污染的问题，研制了一种新型的双功能陶瓷膜生物反应器．该生物反应器的主要特点是采用一种具有双重功能的陶瓷膜作为生物反应器的主要元件，陶瓷膜可以交替地进行曝气和过滤，将膜的在线反冲清洗和生物反应器的供氧曝气结合在一起．考察了不同运行条件下该反应器对COD、氨氮的去除效果．对陶瓷膜的充氧能力进行了实验，测得小孔陶瓷膜、大孔陶瓷膜、砂型曝气头的氧传递系数分别为：0．2315min-1，0．1587min-1，0．0991min-1．     

碳纤维增强陶瓷基复合材料抗氧化涂层研究进展

对碳纤维增强陶瓷材料抗氧化涂层的要求、组成与制备工艺以及最近抗氧化涂层体系的发展做了综述。并且对今后抗氧化涂层的发展作了一些展望。